PhD Thesis: Theoretical Study of Carrier Capture into Semiconductor Quantum Wells

Karol KALNA

Department of Theory of Semiconductor Microstructures
Institute of Electrical Engineering, Slovak Academy of Sciences
Dubravska cesta 9, 842 39 Bratislava, Slovakia

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Summary

We have calculated the ambipolar carrier capture time in a separate confinement heterostructure quantum well (SCHQW) excited by a short laser pulse. This ambipolar capture time incorporates the semiclassical hole capture time and the quantum-mechanical electron capture time. The latter one, calculated for the electron-polar optical phonon (e-pop) interaction, oscillates as a function of the quantum well (QW) width. The calculated ambipolar capture time reasonably agrees with the measured capture time. The analysis of the electron distribution function in the SCHQW barrier shows that the photoexcited electrons are nonthermal before they are captured into the QW.
We have also calculated the electron capture times due to the electron-electron (e-e), electron-hole (e-h) and e-pop interactions for a model laser regime. The calculated capture times oscillate as a function of the QW width with the same period, but with quite different amplitudes. For an electron density of 1011 cm-2 in the QW, the e-e capture time is one to three orders larger and the e-h capture time two to four orders larger than the e-pop capture time. The exceptions are the QW widths near resonance minima, where the e-e capture time is only 2-3 times larger and the e-h capture time 10-100 times larger. With increasing density the e-e capture time decreases and for a high enough density (1012 cm-2) becomes smaller than the e-pop capture time. Therefore, in simulations of the QW lasers the e-e interaction should be taken into account at resonance for any density 1011 cm-2, while the e-h interaction should only be considered at densities ~ 1012 cm-2.
We have also taken into account effects of exchange and degeneracy on the e-e capture. The exchange effect increases the e-e capture time approximately two times while the degeneracy does not change the capture time except for the QW depths and widths near the resonance.
Finally, we have shown that the oscillatory behaviour of the e-e and e-pop capture time has a different physical origin.

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